Molecular Vibrations: The Theory of Infrared and Raman Vibrational Spectra

Molecular Vibrations: The Theory of Infrared and Raman Vibrational Spectra

Molecular Vibrations: The Theory of Infrared and Raman Vibrational Spectra
By Edgar Bright Wilson

Publisher: Dover Publications
Number Of Pages: 388
Publication Date: 1980-03-01
ISBN-10 / ASIN: 048663941X
ISBN-13 / EAN: 9780486639413
Binding: Paperback

This pedagogical classic and essential reference for anyone engaged in research in molecular spectroscopy focuses on the mathematics involved in detailed vibrational analyses of polyatomic molecules. It leads the reader gradually from application of wave mechanics to potential functions and methods of solving the secular determinant. 16 appendices.

Summary: A Classical Book
Rating: 5

This is a classical book on the subject of molecular vibrations. People interested in molecular spectroscopy or Quantum Chemistry should read it. Excellent book!

Summary: probably the best book about molecular vibration
Rating: 5

It is probably the best book about molecular vibrations, cited in many other books.
It treats complex arguments with rigour but at the same time it is able to explain them clearly.

Summary: very good...
Rating: 5

In this one, Wilson writes definitively, math/scientifically, and with sincerity of purpose. Don't get confused by the word 'theory.' There's as much math in here as Born and Wolf's P of O. The only diffenrence is Wilson's is much more algebra-based. The mathematics (i.e. isomorphs) is 'taught', without breaking the flow, and is not assumed that you know the stuff already--- or can find it somewhere else. This book stands out because there is more science in here than names of scientists, and his references are for real. I would also say it was unique because books with titles like 'Molecular Vibrations' are usually skipped over for titles like 'mechanics' or 'quantum theory.' Spectroscopy was a major advancement in science, and it is good to see it skillfully treated with enlightening clarity.

Summary: A MUST HAVE for those dealing with B matrix methods
Rating: 5

This is the original work by E.B.Wilson where the G and F matrix formalism is presented. The G matrix, related to kinetic vibrational energy is built uppon the elements of the B matrix defined from "internal coordinates". Many quantum chemistry software packages use this exact methodology to build normal coordinates. For those working on Quantum Chem Molecular Orbital calculations, this book is a must.

Summary: 1955 classic
Rating: 4

Reissue of original, which was published in 1955, in the pre-computer age. Solid QM description of vibrating polyatomic molecules, and their interaction with EM radiation. The authors exploit group theory (molecular symmetry) to reduce the calculational work as much as possible. Good introduction to the use of finite groups, e.g. how to exploit the hexagonal symmetry of the benzene molecule.

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