郑思珣教授
郑思珣教授郑思珣教授、博士生导师。1997年获中国科技大学高分子化学与物理专业博士学位。1992年7月起分别任中国科技大学高分子科学与工程系助教、讲师(1995年)、副教授(1998年)。分别于1996年和1998年两次赴香港科技大学化学工程系做访问学者。1999年1月, 获德意志研究联合会资助,赴德国高分子研究所(Deutsches Kunststoff-Institut, Darmstadt)及达姆施塔特工业大学(Technische Universitaet Darmstadt)物理系从事博士后研究。1999年9月转至美国加州大学欧文分校(University of California, Irvine, USA)化学系,为National Science Foundation (NSF)博士后研究员。2001年9月加入上海交通大学化学化工学院任高分子科学与工程系教授。先后承担或参加国家自然科学基金、中科院院长基金以及国家部委科研基金的研究工作; 2002年获“教育部优秀青年教师资助计划”基金支持。2004年获上海市“曙光学者”称号。已在Macromolecules, Polymer, Journal of Polymer Science等国际高分子核心学术期刊发表SCI收录的论文90多篇,国际学术会议论文10余篇。论文被国际同行引用(他引)超过500次。
主要研究方向:
热固性聚合物的结构与性能研究:相容性及相行为、分子组装结构以及断裂力学;
含笼型硅氧烷(Polyhedral Oligomeric Silsesquioxanes, POSS)的聚合物的结构与性能研究;
结晶聚合物的固化(Solidification)过程研究;
具有拓卜结构高分子的合成及其微结构研究;
高分子固体核磁共振波谱研究(H-1、H-2、Si-29、C-13 CP/MAS NMR等):a)多组分高分子体系的相结构及其大分子动力学研究;b)有机/无机纳米复合材料中的组分间相互作用研究。
近期发表的部分论文:
Zhiguang Xu, Sixun Zheng*, "Reaction-induced Microphase Separation in Epoxy Thermosets
containing Poly(epsilon-caprolactone)- block-poly(n-butyl acrylate) Diblock Copolymer", Macromolecules, 2007, 40, 2548
Yong Ni, Sixun Zheng*, "Supramolecular Inclusion Complexation of POSS-capped Poly(epsilon-caprolactone) with alfa-Cyclodextrin", Journal of Polymer Science, Part A: Polymer Chemistry, 2007, 45, 1247
Jiangfeng Mu, Yonghong Liu, Sixun Zheng*, "Inorganic-Organic Interpenetrating Polymer Networks involving Polyhedral Oligomeric Silsesquioxane and Poly(ethylene oxide)", Polymer, 2007, 48, 1176
Jiangfeng Mu, Sixun Zheng*, "Poly(N-isopropylacrylamide) Nanocrosslinked by Polyhedral Oligomeric Silsesquioxane: Temperature-Responsive Behavior of Hydrogels", Journal of Colloid and Interface Science, 2007, 307, 377
Yonghong Liu, Yong Ni, Sixun Zheng* , "Morphology and Properties of Polyurethane Networks Modified with Octa(propylglycidyl ether) Polyhedral Oligomeric Silsesquioxane", Macromol. Chem. & Phys., 2006, 207, 1842
Fanliang Meng, Sixun Zheng* , et al., "Epoxy Resin Containing Poly(ethylene oxide)-block-Poly(epsilon-caprolactone) Diblock Copolymer: Effect of Curing Agents on Nanostructures", Polymer, 2006, 47, 7590
Yonghong Liu, Xingtian Yang, Weian Zhang, Sixun Zheng* , "Star-shaped Poly(epsilon-caprolactone) with Polyhedral Oligomeric Silsesquioxane Core", Polymer, 2006, 47, 6814.
Fanliang Meng, Sixun Zheng* et al., "Formation of Ordered Nanostructures in Epoxy Thermosets: a Mechanism of Reaction-induced Microphase Separation", Macromolecules, 2006, 39, 5072
Bingquan Liu, Weian Zhang and Sixun Zheng*, "Competitive Specific Interactions in Miscible Blends of Poly(hydroxyether terephthalate ester) and Poly(4-vinylpyridine)", Journal of Polymer Science, Part B: Polymer Physics, 2006, 44, 1618
Jia Shen, Sixun Zheng*, “Comparative Studies on Miscibility and Phase Behavior of Linear and Star Poly(2-methyl-2-oxazoline) Blends with Poly(vinylidene fluoride)”, Journal of Polymer Science, Part B: Polymer Physics, 2006, 44, 942
Fanliang Meng, Sixun Zheng* et al., "Nanostructured Thermosetting Blends of Epoxy Resin and Amphiphilic Poly(epsilon-caprolactone)-b-Polybutadiene-b-Poly(epsilon-caprolactone) Triblock Copolymer", Macromolecules, 2006, 39, 711
Yonghong Liu, Sixun Zheng* "Inorganic-Organic Nanocomposites of Polybenzoxazine with Octa (propylglycidyl ether) Polyhedral Oligomeric Silsesquioxane", Journal of Polymer Science, Part A: Polymer Chemistry, 2006, 44, 1168.
Yong Ni, Sixun Zheng*, "Epoxy Resin Containing Polyphenylsilsesquioxane: Preparation, Morphology and Thermomechanical Properties", Journal of Polymer Science, Part A: Polymer Chemistry, 2006, 44, 1093.
Yonghong Liu, Sixun Zheng*, "Epoxy Nanocomposites with Octa (propylglycidyl ether) Polyhedral Oligomeric Silsesquioxane", Polymer, 2005, 46, 12016.
Yong Ni, Sixun Zheng*, "Epoxy Resin Containing Octamaleimidophenyl Polyhedral Oligomeric Silsesquioxane", Macromolecular Chemistry & Physics, 2005, 206, 2075.
Bingquan Liu, Weian Zhang, Sixun Zheng*, "Poly(hydroxyether terephthalate ester): Synthesis, Characterization and Competitive Specific Interactions in Mixtures with Poly(ethylene oxide)", Polymer, 2005, 46, 10574.
Hongzhi Liu, Sixun Zheng*, Kangming Nie, "Morphology and Thermomechanical Properties of Organic-Inorganic Hybrid Composites involving Epoxy Resin and an Incompletely-Condensed Polyhedral Oligomeric Silsesquioxane", Macromolecules, 2005, 38, 5088
Yong Ni, Sixun Zheng*, "Influence of Intramolecular Specific Interactions on Phase Behavior of Epoxy Resin and Poly(epsilon-caprolactone) Blends Cured with Aromatic Amines", Polymer, 2005, 46, 5828
Kangming Nie, Sixun Zheng, Fei Lu and Qingren Zhu, "Inorganic-Organic Hybrids involving Poly(epsilon-caprolactone) and Silica Network: Hydrogen Bonding Interactions and Isothermal Crystallization Kinetics", Journal of Polymer Science, Part B: Polymer Physics, 2005, 41, 2594
Yonghong Liu, Fanliang Meng, Sixun Zheng*, "Poly(4-vinylpyridine) Nanocrosslinked by Polyhedral Oligomeric Silsesquioxane", Macromolecular Rapid Communications, 2005, 26, 920.
Minghua Yin, Sixun Zheng*, "Ternary Thermosetting Blends of Epoxy Resin, Poly(epsilon-caprolactone) and Poly(ethylene oxide), Macromolecular Chemistry & Physics, 2005, 206, 929
Hongzhi Liu, Sixun Zheng*, "Polyurethane Networks Nanoreinforced by Polyhedral Oligomeric Silsesquioxane", Macromolecular Rapid Communications, 2005, 26, 196
Hongzhi Liu, Weian Zhang and Sixun Zheng*, "Montmorillonite Intercalated by Ammonium of Octaaminopropyl Polyhedral Oligomeric Silsesquioxane and Its Nanocomposites with Epoxy Resin", Polymer, 2005, 46, 157
Han Lu, Sixun Zheng*, "Miscibility and Intermolecular Specific Interactions in Thermosetting Blends of Bisphenol S Epoxy Resin with Poly(ethylene oxide)", Journal of Polymer Science, Part B: Polymer Physics, 2005, 43, 359
Yong Ni, Sixun Zheng* , "A Novel Photocrosslinkable Polyhedral Oligomeric Silsesquioxane and its Nanocomposites with Poly(vinyl cinnamate)", Chemistry of Materials, 2004, 16, 5141
Kangming Nie, Wenming Pang and Sixun Zheng, ''Nonisothermal Crystallization Kinetics of Poly(e-caprolactone) in Hydrogen Bond Coupled Polymeric-Inorganic Hybrid Materials'', Polymer International, 2005, 54, 327
Yong Ni, Sixun Zheng* and Kangming Nie, ''Morphology and Thermal Properties of Inorganic-Organic Hybrids Involving Epoxy Resin and Polyhedral Oligomeric Silsesquioxanes'', Polymer, 2004, 45, 5557
Han Lu, Sixun Zheng* and Qipeng Guo, "Thermosetting Blends of Polybenzoxazine and Poly(episilon-caprolactone): Phase Behavior and Intermolecular Specific Interactions", Macromolecular Chemistry & Physics, 2004, 205, 1547
Lindi Hu, Han Lu and Sixun Zheng*, "Effect of Crosslinking on Intermolecular Interactions in Thermosetting Belnds of Epoxy Resin and Poly(ethylene oxide)", Journal of Polymer Science, Part B: Polymer Physics, 2004, 42, 2567
Sixun Zheng*, Kangming Nie and Qipeng Guo, ''Miscibility and Phase Separation In Blends of Phenolphthalein Poly(aryl ether ketone) and Poly(ethylene oxide): A Differential Scanning Calorimetric Study'', Thermochimica Acta, 2004, 419, 267
Han Lu, Sixun Zheng*, Bing Zhang and Xiaozhen Tang, ''Miscibility and Intermolecular Specific Interactions in Blends of Poly(hydroxyether sulfone) and Poly(N-vinyl pyrrolidone)'', Macromolecular Chemistry & Physics, 2004, 205, 834
Han Lu, Sixun Zheng* and Guohua Tian, ''Poly(hydroxyether sulfone) and Its Blends with Poly(ethylene oxide): Miscibility, Phase Behavior and Hydrogen Bonding Interactions'', Polymer, 2004, 45, 2897
Han Lu, Sixun Zheng*, ''Miscibility and Phase Behavior in Thermosetting Blends of Polybenzoxazine and Poly(ethylene oxide)'', Polymer, 2003, 44, 4683
Sixun Zheng*, Han Lu, Chunxia Chen, Kangming Nie and Qipeng Guo, ''Epoxy Blends with Poly(ethylene oxide) and Poly(epsilon-caprolactone) Cured with 1,3,5-Trihydroxybenzene: Miscibility and Intermolecular Interactions'', Colloid & Polymer Science, 2003, 281, 1015
Sixun Zheng*, Rong Gao and Qipeng Guo, ''Epoxy Resin containing the Poly(sily ether): Preparation, Morphology and Mechanical Properties'', Journal of Applied Polymer Science, 2003, 89, 505
Sixun Zheng*, Haifeng Zheng and Qipeng Guo, ''Epoxy Resin / Poly(epsilon-caprolactone) Blends Cured with 2,2-bis [(4-(4-amino-phenoxy)) phenyl] propane: I. Miscibility and Crystallization Kinetics'', Journal of Polymer Science, Part B: Polymer Physics, 2003, 41, 1085
Sixun Zheng*, Qipeng Guo and Chi-Ming Chan, ''Epoxy Resin / Poly (epsilon-caprolactone) Blends Cured with 2,2-bis[(4-(4-aminophenoxy)) phenyl] propane. II. Studies by Fourier Transform Infrared and Carbon-13 Cross Polarization / Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy'', Journal of Polymer Science, Part B: Polymer Physics, 2003, 41, 1099
Sixun Zheng*, Shuping Ai and Qipeng Guo, ''Poly(hydroxyether of phenolphthalein) and its Blends with Poly(ethylene oxide)'', Journal of Polymer Science, Part B: Polymer Physics, 2003, 41, 466
Sixun Zheng*, Yongli Mi, ''Miscibility and Intermolecular Specific Interactions in Blends of Poly (hydroxyether of bisphenol A) and Poly(4-vinyl pyridine)'', Polymer, 2003, 42, 1067
Sixun Zheng*, Qipeng Guo and Yongli Mi, ''Miscibility and Phase Behavior in Blends of Phenolphthalein Poly(ether sulfone) and Poly(hydroxyether of bisphenol A)'', Polymer, 2003, 44, 867
Sixun Zheng*, Jiahua Li and Qipeng Guo, ''Miscibility in Blends of Poly(methyl methacrylate) and the Poly(silyl ether) as Investigated by DSC and 13C CP/MAS NMR Spectroscopy'', Journal of Macromolecular Science, Part B: Physics, 2003, 42, 353
专利:
Joseph D. Lichtenhan, Frank J. Feher, Joseph J. Schwab, Sixun Zheng (2005), "Reactive Grafting and Compatibilization of Polyhedral Oligomeric Silsesquioxanes", United States Patent, 6933345, Issued on Aug. 23, 2005.
郑思珣,杨星天(2005), "聚羟基醚酮及其制备方法", 中国发明专利(CN1693337), 2005, 11, 09.
通讯地址:
上海市闵行区东川路800号
上海交通大学化学化工学院高分子科学与工程系
邮政编码:200240
电话: 86-21-54743278
传真: 86-21-54741297
Email: szheng AT sjtu DOT edu DOT cn
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