【书籍名称】：Heterogeneous Enantioselective Hydrogenation: Theory and Practice (Catalysis by Metal Complexes)
【作 者】：Evgenii Klabunovskii, Gerard V. Smith, Ágnes Zsigmond
【出 版 社】：Publisher: Springer
【版次时间】：Publication Date: 2006-10-05
Number Of Pages: 304
ISBN-10 / ASIN: 1402042949
ISBN-13 / EAN: 9781402042942
Binding: Hardcover
Heterogeneous Enantioselective Hydrogenation: Theory and Practice reviews the development of enantioselective hydrogenation reaction catalysts. It looks at the first relatively ineffective catalysts right through to modern highly effective enantioselective catalytic systems, comparable in their efficiency to chiral metal complexes and enzymatic systems. The book begins with a summary of the first work on heterogeneous metal catalysts, which showed only the principal possibilities of enantioselective reactions. It then elaborates on metal catalysts which have enantioselectivities close to 100%. Finally, the practical utilization of chiral catalytic systems in processes of hydrogenation is described. The alpha- and beta-hydroxy carboxylic acid esters produced are precursors for manufacturing many synthones used for medicines as well as for monomers used for biodegradable polyesters, both of which have important practical applications.
The volume summarizes more than 800 scientific papers in the field of enantioselective catalytic hydrogenation reactions, mainly those using heterogeneous metal catalysts. It provides detailed explanations of special techniques for the preparation of effective dissymmetric catalysts which provide highly efficient catalytic systems. This book differs from previous publications by virtue of the recommendations for the practical utilization of recently described preparations of metal catalysts.
Table of contents （共 7 章 ）
Front Matter
Chapter 1： ASYMMETRIC ADSORPTION ON MINERALS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 2： HETEROGENEOUS HYDROGENATION CATALYSTS BASED ON QUARTZ
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 3：HETEROGENEOUS CATALYSTS SUPPORTED ON CHIRAL CARRIERS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 4：HYDROGENATION ON CATALYSTS BASED ON Ni AND BIMETALS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 5：ASYMMETRIC HYDROGENATION OF 2-OXOCARBOXYLIC ACID ESTERS AND UNSATURATED CARBOXYLIC ACIDS ON MODIFIED PT AND PD CATALYSTS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 6：ELECTROCHEMICAL ENANTIOSELECTIVE REDUCTIONS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Chapter 7：PRACTICAL ASYMMETRIC CATALYTIC REACTIONS
EVGENII KLABUNOVSKII, GERARD V. SMITH and ÁGNES ZSIGMOND
Back Matter
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